Being a non-visa national, she applies at the Port of Entry as a family visitor who is maintaining her relationship with her husband. All aspects of Paragraph 41 apply.
If she has a pejorative immigration history, or otherwise cannot satisfy Paragraph 41, she applies at a British Consulate General for entry clearance as a family visitor who is maintaining her relationship with her husband.
In both cases, she is entitled to right of appeal, either in the UK or abroad. Non-family visitors do not get appeal rights.
To the notion of lying about her marital status, she not only forfeits her appeal rights, she also would fail to disclose a material fact regarding her intent in the UK, and doing that flirts with a 10 year ban for deception.