Your S-corp is likely to become a UK corp for UK tax purposes. You are setting yourself up for a big, big, fall. Get professional advise IMMEDIATLY from someone who understands Expatriate Taxation, Tax Equalization, UK corporate tax, US corporate tax, UK personal tax, and US personal tax. I'll give you a hint: PWC is working for your boss, not for you. They're advice may not be impartial, and the team working expatriate taxation may not have anyone familiar with the UK taxation of US corporations.
Do NOT rely on an e-forum. Do NOT rely on your boss's free tax help. Pay for and take real advise from real-world accountants who deal with your situation on a daily basis.