Guya is more of an expert on this topic than I am, so he will correct me if I have it wrong.
1) You can not include ANY commuting. The first trip of the day to the location you will be working and the last trip of the day to go home do not count. If you are working from home, your first and last trip may not count as commuting; it depends on how "commuting-like" these trips are. You would need to ask a specialist in this area to make sure.
2) Each trip must be necessary for business. For example, was it really necessary to drive out to see Client Whosis in September, or could you have handled everything by fax, telephone, etc.? Was this trip actually commuting rather than a separate business trip? And if it WAS really necessary, why did your employer not reimburse you for the cost? If you're self-employed, why did you not bill the client for the trip? You would have to justify your position to the Inland Revenue on these points, as well as have proof of your mileage, the business nature of the trip, who you met with, and so forth in the event this item is selected for an inquiry.
3) If your employer does not reimburse you, you take a claim as a deduction against your income. This reduces your taxable income; it does not reduce your tax directly. Thus, driving 2500 miles x .40/mile = £1,000 deduction. In this example, if you are in the 40% bracket, this saves you £400. If you are in the 22% bracket, you save £220. Your former employer may have made internal adjustments which pushed the allowance up or down on your paycheque; these would not apply to you in your current situation.