I think that would be okay, though her employer should explain the different pay date in their letter, so that UKVI aren't confused by why she hasn't been paid on the normal date.
After all, for Category B, you just need to show a total of £18,600 earned at any point in the last 12 months, from any and all jobs, so for that part of the requirement, it shouldn't matter WHEN she got paid.
For the other part of the requirement, since she hasn't been with her current employer for 6 months yet, she just needs to show that her current and future salary will be the equivalent of £18,600 per year, regardless of what date she is paid each month.