Apart from needing an ITIN you'd both need to file an election under section 6013(g) with the first return you choose to file jointly.
This would mean including all his worldwide income & gains on your joint US returns - including things that are tax-free here suich as gambling winnings, lottery prizes, ISAs, gain on sale of home, gain on repaying mortgage, employer pension contributions etc; so you'd need to figure out if it would cost you money to make this election.