If you're in London, the Book and Comic Exchange in Notting Hill is a pretty good bet. They always seem to have a good selection of used books and based on experience, they'll buy your books for a relatively fair price. They'll also give you more if you simply want store credit.
And, as a bonus, there was a Book Warehouse five minutes away, the last time I was there. Like other posters have said, they don't buy books but you can sometimes hit the jackpot with just remaindered, really cheap hardcovers.