Hi JVJM,
Currently what you're saying is quite vague in terms of the sheer number of potential places you could move to that are within an hour or so of LB/Waterloo. You could literally move to ANY similar small village or a town within a couple of miles around the M25, or you could just find another place to rent/live in the same village you're at now!
You'll need to bring into the equation things like practical aspects as well as nice to haves. Do you want a bigger place? a more higher end place? smaller? a quiet village? a more busier and happening place? would you like ot be closer to parks and leisure activities? want more convenience etc etc.
There's plenty of people on this forum who are more than happy living in the outskirts of London and just as many more who are a little further out. Have a sit down with your better half and discuss the things that are important to you for the move and start to draw up a shortlist of potential places from researching here and other websites, word of mouth etc recommendations and take it from there.
Lastly, Slough IS the centre of the universe and I can recommend it - contrary to what some UKY say about it!
Cheers, DtM! West London & Slough UK!