Well, the differences are that a civil ceremony is performed by a registrar, and it is without any religeous tone, wording, prayer, etc by law. It's a legal ceremony as you would have if you went to the Justice of the Peace in the US. The other option is a church ceremony, where the ceremony is performed either in a church, or by a church official/priest/vicar, etc.
You could always have a 'blessing' ceremony later, after you are already married, but if you wanted to do it in a church over here, you would most likely have to have the vicar perform it, rather than your brother. You could always do a 'blessing' at another venue, but it's mostly ceremonial, rather than an official thing, so I don't think it would be a problem.
Congrats on your upcoming marriage