Total 2006 payments = total 2006 payments TO THE US GOVERNMENT. So your UK PAYE and NI is ignored. If you've been in the UK all year, it's not likely you've paid anything. If you moved this year, then copy the info from your 2006 US W2.
Estimated Tax Liability = how much you think you owe the US. Most overseas filers owe very little. If you're not sure, pay a few hundred - you'll get a refund if you overpay.