Hi groovy yank!
I haven't got 'specific' help for you as I dont usually get any problems whatsoever with my DVD/VOB to MPEG rips. However I do have some pointers.
Sync issues can be due to your processor not 'being up to the task' - Video encoding and conversion is a really intensive process and susceptible to outside interference. Shut down ALLLL porgrams on your PC to free up as much resources as possible. Ideally, you should have as much RAM as possible and some more RAM too!
dont have any other programs running when you do the conversion, I'd advise unplugging the internet and switching off security software as well whilst the process goes through - obvously, when you want to go back on the net, switch the security software back on!
I use a program called Video Vault for my Rips (also looking to get CloneDVD)- i've never had an problems with it. It will import into MPEG format from a multitude of sources and then that can be re-encoded if needed (ipod, psp and PDA formats for instance) With non copy protected source material you should be able to import rightaway.
Bear in mind, I've not tried importing from sources such as video tape and/or movie cameras etc, there may be interim steps needed - look at what you have to decide on what's best.
finally - check out a site called
http://www.afterdawn.com/ it a site where everything to do with PC and media files and encoding/recoding can be and is discussed - it's pretty good - nip over to the forums and there's a wealth of info. CloneDVD gets very rave reviews indeed! so much so that I'm probably going to convert!
Hope this helps! Good luck!
DtM! West London & Slough UK!