Thanks, but it's just a little bit hard to argue with her actual experiences in both places isn't it? She has told me some absolute horror stories in regards to both places while living there. I know that there is a rivalry between both locations. My wife was in a cab with me in Edinburgh and the cabbie didn't understand or pretended to not understand what she was saying even though she grew up 40 miles away. 
Like I mentioned in my last response, I didn't like the American Goth looking suburb that I observed in Dunfermline and the posh/stuck up feeling I noticed in Edinburgh.
I like down to earth, leave me alone type of living where possible. If I am forced to interact with other humans in close proximity (which I am trying to avoid) I prefer down to earth folks. Not to say that everyone in Dunfermline/Fife is going to explicitly meet those stereotypes, but I'd rather not find out that I am more right than wrong.
Hi there as someone who is married to a Glaswegian myself, I can totally relate to your circumstances around Scotland (especially in Edinburgh). Correct me if I'm wrong but you did say that your wife was born and raised in Glasgow right? If that's the case I'm almost shocked that she wants to leave, because every Glaswegian that I've ever met never wants to leave the place!
Any how my husband also grew up in a very bad area (Possil) but would thoroughly disagree with the stance your spouse has on the education. From his take he had a fantastic educational experience even in the rough area where he grew up. His education afforded him the opportunity to be accepted int Glasgow uni, cambridge etc,...but like any Glaswegian he turned it down and decided to go into gas engineering instead, finding that those universities had a tendency to think they were better than the working class.
Of course, everyone has their own specific experiences with their upbringing.
I went to Glasgow to study school and that's where I met my husband. I fell in love with the city and it's culture, because I believe it has something for everyone. We just bought a flat there and am waiting for my spouse visa to be granted. For me, I can not wait to have my children there and have them raised in the city of Glasgow. I think that they will have many open opportunities to explore their potential. People call me crazy because I'm from Boston and they think I should have my family here, but I would pick Glasgow time and time again!
As for your profession I'm sorry I don't have any experience in that I'm in hospitality and my husband is a gas engineer. However I would think that you would want to be in a city where there are more companies that require the assistance of IT...but again I'm completely ignorant of your profession.
I hope my post helps you with at least a little insight!