Thank you! Yes I had a fiancee Visa.
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I did that too. The appointment isn't too long and where you'll have to go depends on where you live. I'm in the East Midlands and had to go to Nottingham to do mine, about 45 minutes away? They can only do it at specific JobCentre Pluses. So it's kind of annoying.
You'll need your spouses NINo for your application, just an FYI.
It does take about a month to get. You can apply for jobs before you get it as long as the job isn't an online application that requires that number. But you want to get it ASAP since it's how they figure out how much to tax you.
Get it in your married name if that's what you plan to use in the UK. I got mine in my maiden name, as that's what's on my passport, but I was using my married name and I had to call HMRC to have them change it. Kind of a pain in the bum.