Get a copy of the Reader's Digest DIY manual - it is very good and refreshingly honest, i.e. it will tell you if a job is going to be difficult and one which you may want to get some professional help. It also shows you diagrams of typical British heating/water/electric systems and talks through the basics of how they operate and how they can go wrong.
Bleeding radiators is easy, but can be messy as water can end up everywhere.
I'd get the people who installed the system back in to have a look at, but if you don't trust them (!!), ask people in your area who they can recommend. I can recommend a great plumber/heating engineer in Walthamstow, east London, who sorted out our ageing heating system. A recommended engineer is worth 100 dodgy engineers, so ask around your area.