If I understand it correctly, when the new rules eventually do come into effect, she will have a couple of years to obtain citizenship under the old rules since she has ILR under the old rules. If she doesn't do it by that time, then she'll have to obtain it under the new rules. If there is some Thai law that doesn't allow her to take on another citizenship without losing her Thai citizenship then she would be able to remain on ILR forever. However, if, as others think, there is no problem with her having dual citizenship, then, personally, I'd go for British citizenship soon...it's never going to be cheaper than it is now for one thing! The prices will keep going up and the hoops will get more numerous and smaller (harder to jump through)!
We just got a survey from our MP asking our opinion about points-based citizenship and our thoughts on it...