If you're talking of drawdown then there is the one-time 25% HMRC tax free amount. The rest is taxable and can be withdrawn whenever you like.
If you take the pension as a number of lump sums, then each withdraw would have a 25% tax free element.
With drawdown, you can take any retirement distributions as a regularly scheduled withdraw, (usually no more then a year apart), or simply dip in as and when you like.
If you take the lump sum method, then there is usually no scheduled payments and its up to you when you withdraw and the amount.
Be careful of not falling foul of HMRC MPAA rules with flexibly accessing your retirement account. A lifetime annuity is one way to overcome that hurdle.