Is his name on all those receipts you have? If they do, then it might pass, but if they just showed that X amount was paid on Y date, there might be an issue since you need to prove that *he* paid them and not someone else.
But really, I hate to sound like a broken record, but a bank statement would be far easier, and more solid than a whole bunch of receipts. One bank statement per month can do what all those receipts can, and it's not really difficult to open up a basic checking account in the UK. If you include a load of receipts, the ECO has to try and tally everything up and see if it goes with the budget and such. With receipts, you might have a lot of explaining to do as where a simple bank statement every month would speak for you and your husband.